<正>A radial distribution function for attractive hard-core systems is obtained from the equilibrium of a molecular pair between local and bulk environments.With this function, a general model is established for the coordination number(CN) and local composition(LC) of square-well fluids.It meets the low-density,high-density and high-temperature limit conditions,as well as the unlike pair conservation and quasi-chemical equilibrium conditions. It also has some other features that many other models do not have:(1) its CN and LC expressions contain all pair potentials;(2) it yields temperature-dependent CN and LC for closely packed mixtures with different pair potentials;(3) its energy parameter is the difference of the total potentials of one pair in local and bulk environments,not the difference of two pair potentials.This model can accurately predict the CN,LC and compressibility factors of square-well fluids from computer simulation over a wide range of density,well width(λ=1-2) and diameter ratio.For the caseλ=1.5,this model is better than or comparable with semiempirical models;in other cases,it is far better than semi-empirical models.It does not need any empirical parameter for LC prediction.For the prediction of CN and compressibility factors,it only needs the smoothed radial distribution function of pure hard-sphere fluids. It also gives excellent results for lattice gases and highly nonideal lattice mixtures.