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手性三菲咯啉合镍与DNA的立体选择性研究

宋玉民;康敬万;王志华;卢小泉;高锦章

  Binding ofΔ ,Λ[Ni(phen)3]2+to calf thymus DNA was studied by circular dichroism and electrochemical methods. TheselectivityofΔisomer in binding to a righthanded duplex of DNA was found. Binding constants and binding site sizes forΔ andΛ [Ni(phen)3]2+with DNA were determined from voltammetric data.……   
[关键词]:;菲咯啉;DNA
[文献类型]:期刊
[文献出处]: 《高等学校化学学报1999年12期
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