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An efficient method to synthesize HMX by nitrolysis of DPT with N_2O_5 and a novel ionic liquid


  A novel polyethylene glycol(PEG)-200-based dicationic acidic ionic liquid(PEG_(200)-DAIL) was used to synthesize HMX from DPT by nitrolysis with N_2O_5.It was found that either N_2O_5 or PEG_(200)-DAIL could improve the yield.Furthermore,the combined use of PEG_(200)-DAIL and N_2O_5 could increase the yield of HMX to 64%with the used quantity of HNO_3 decreased dramatically.……   
[关键词]:DPT;Nitrolysis;N_2O_5;Acidic ionic liquid
[文献类型]:期刊
[文献出处]: 《Chinese Chemical Letters2009年04期