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“Random Coil” Proton Chemical Shift of Deoxyribonucleic Acids.

Sik Lok Lain;Lai Nang Ip

  With the combination of the aromatic proton chemical shills of the central nucleotides in triplets and the correction factors determined for the next nearest neighbor effect, the aromatic proton chemical shills of“random coil”DNA sequences can be predicted accurately.The aromatic proton chemical shifts of 16 unstructured single-strand DNA sequences containing all 64 different types of triplets have been measured.……