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A New Maleamide Bridged Carbazole Chromogenic-sensor Based on Proton Transfer Signaling Mode


  A Maleamide bridged carbazole receptor was designed and synthesized, the interactions between the receptor and anions, such as Ac-, H2PO4-, OH-, F-, Cl-, Br- and I- in DMSO were investigated by UV-Vis spectroscopy and 1H NMR titration. The results of UV-Vis spectral studies indicate that interactions existed between receptor and anions, which induced remarkable color changes. The 1H NMR titration indicated amide moiety of the receptor was deprontonated first when a small quantity of anions such as Ac-, H2PO4-, F- were added; however, the carbazole N―H was gradually deprontonated upon the addition of anions.……   
[关键词]:Anion receptor;Colorimetric;Supramolecular chemistry
[文献类型]:期刊
[文献出处]: 《Chemical Research in Chinese Universities2008年03期
[格式]:PDF原版; EPUB自适应版(需下载客户端)