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新型超分子化合物C_6H_(20)N_2O_(64)P_2Mo_(18)·8H_2O的晶体结构及电催化作用

刘景华;辛明红;王恩波;彭军;毕丽华

  A novel compound formulated [NH2(CH2)4CHNH2COOH]H6P2Mo18O62 has been synthesized and its structure has been characterized, which is the first example of aminoacid-heteropolyacid species. Crystal system is orthorhombic, space group P21212, unit cell dimensions: α=1. 572 2(3) nm, b=2.118 1 (4) nm, c=1.238 3(3) nm, α=90.04(3)°, β=90.00 (2)°, γ= 89. 99 (3)°, V = 4.123 6(14) nm3, Z=2, D0=2.437×103 kg/m3, R=0.038 7. Experimental result shows that the title compound has electrocatalysis reactivity.……   
[关键词]:超分子化合物;晶体结构;电催化作用
[文献类型]:期刊
[文献出处]: 《高等学校化学学报1999年09期