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Formation of a three-dimensional bispyridyl based metal-organic architecture containing unique Ag…Ag(d~(10)-d~(10))interactions


  A novel co-ordination polymer based on IB metal thiocyanates,[Ag_2(NCS)_2(4,4 -bipy)]_n(1)(4,4 -bipy=4,4 -bispyridine),has been synthesized by the pre-assembly method and characterized by X-ray crystallography.The complex exists as a three- dimensional network consisting of(AgSCN)_n undulating layers linked by 4,4 -bipy bridges.……